File size: 14,678 Bytes
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data_1888095
_audit_creation_date              2025-01-20
_audit_creation_method            'Materials Studio'
_symmetry_space_group_name_H-M    'P1'
_symmetry_Int_Tables_number       1
_symmetry_cell_setting            triclinic
loop_
_symmetry_equiv_pos_as_xyz
  x,y,z
_cell_length_a                    14.1630
_cell_length_b                    13.8690
_cell_length_c                    7.4930
_cell_angle_alpha                 90.0000
_cell_angle_beta                  94.7800
_cell_angle_gamma                 90.0000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
F1     F     0.41747   0.41536   0.50000   0.01000  Uiso   1.00
F2     F     0.50989   0.50002   0.73391   0.01000  Uiso   1.00
F3     F     0.41747   0.58464   0.50000   0.01000  Uiso   1.00
C4     C     0.68052   0.14651   0.63773   0.01000  Uiso   1.00
H5     H     0.70881   0.16808   0.52958   0.01000  Uiso   1.00
H6     H     0.62907   0.19030   0.66309   0.01000  Uiso   1.00
H7     H     0.65572   0.08087   0.61944   0.01000  Uiso   1.00
C8     C     0.75349   0.14693   0.79106   0.01000  Uiso   1.00
C9     C     0.75910   0.19535   0.95517   0.01000  Uiso   1.00
C10    C     0.68990   0.26364   0.01986   0.01000  Uiso   1.00
C11    C     0.67841   0.36082   0.97210   0.01000  Uiso   1.00
C12    C     0.73167   0.42231   0.85120   0.01000  Uiso   1.00
H13    H     0.68691   0.45856   0.77008   0.01000  Uiso   1.00
H14    H     0.77105   0.38119   0.78101   0.01000  Uiso   1.00
H15    H     0.77202   0.46766   0.92291   0.01000  Uiso   1.00
N16    N     0.83080   0.09220   0.78621   0.01000  Uiso   1.00
H17    H     0.84388   0.05483   0.69639   0.01000  Uiso   1.00
N18    N     0.60784   0.39589   0.06070   0.01000  Uiso   1.00
C19    C     0.89121   0.19126   0.22266   0.01000  Uiso   1.00
H20    H     0.90027   0.13294   0.29596   0.01000  Uiso   1.00
H21    H     0.85176   0.23729   0.28233   0.01000  Uiso   1.00
H22    H     0.95280   0.22070   0.20663   0.01000  Uiso   1.00
C23    C     0.84413   0.16539   0.04519   0.01000  Uiso   1.00
C24    C     0.62253   0.24419   0.14141   0.01000  Uiso   1.00
C25    C     0.59980   0.15257   0.23376   0.01000  Uiso   1.00
H26    H     0.59482   0.16551   0.36145   0.01000  Uiso   1.00
H27    H     0.65011   0.10528   0.22019   0.01000  Uiso   1.00
H28    H     0.53968   0.12683   0.18061   0.01000  Uiso   1.00
N29    N     0.88530   0.10320   0.93930   0.01000  Uiso   1.00
N30    N     0.57469   0.32598   0.16335   0.01000  Uiso   1.00
H31    H     0.52867   0.33305   0.23421   0.01000  Uiso   1.00
F32    F     0.91747   0.91536   0.50000   0.01000  Uiso   1.00
F33    F     0.00989   0.00002   0.73391   0.01000  Uiso   1.00
F34    F     0.91747   0.08464   0.50000   0.01000  Uiso   1.00
C35    C     0.18052   0.64651   0.63773   0.01000  Uiso   1.00
H36    H     0.20881   0.66808   0.52958   0.01000  Uiso   1.00
H37    H     0.12907   0.69030   0.66309   0.01000  Uiso   1.00
H38    H     0.15572   0.58087   0.61944   0.01000  Uiso   1.00
C39    C     0.25349   0.64693   0.79106   0.01000  Uiso   1.00
C40    C     0.25910   0.69535   0.95517   0.01000  Uiso   1.00
C41    C     0.18990   0.76364   0.01986   0.01000  Uiso   1.00
C42    C     0.17841   0.86082   0.97210   0.01000  Uiso   1.00
C43    C     0.23167   0.92231   0.85120   0.01000  Uiso   1.00
H44    H     0.18691   0.95856   0.77008   0.01000  Uiso   1.00
H45    H     0.27105   0.88119   0.78101   0.01000  Uiso   1.00
H46    H     0.27202   0.96766   0.92291   0.01000  Uiso   1.00
N47    N     0.33080   0.59220   0.78621   0.01000  Uiso   1.00
H48    H     0.34388   0.55483   0.69639   0.01000  Uiso   1.00
N49    N     0.10784   0.89589   0.06070   0.01000  Uiso   1.00
C50    C     0.39121   0.69126   0.22266   0.01000  Uiso   1.00
H51    H     0.40027   0.63294   0.29596   0.01000  Uiso   1.00
H52    H     0.35176   0.73729   0.28233   0.01000  Uiso   1.00
H53    H     0.45280   0.72070   0.20663   0.01000  Uiso   1.00
C54    C     0.34413   0.66539   0.04519   0.01000  Uiso   1.00
C55    C     0.12253   0.74419   0.14141   0.01000  Uiso   1.00
C56    C     0.09980   0.65257   0.23376   0.01000  Uiso   1.00
H57    H     0.09482   0.66551   0.36145   0.01000  Uiso   1.00
H58    H     0.15011   0.60528   0.22019   0.01000  Uiso   1.00
H59    H     0.03968   0.62683   0.18061   0.01000  Uiso   1.00
N60    N     0.38530   0.60320   0.93930   0.01000  Uiso   1.00
N61    N     0.07469   0.82598   0.16335   0.01000  Uiso   1.00
H62    H     0.02867   0.83305   0.23421   0.01000  Uiso   1.00
F63    F     0.58253   0.41536   0.50000   0.01000  Uiso   1.00
F64    F     0.49011   0.50002   0.26609   0.01000  Uiso   1.00
F65    F     0.58253   0.58464   0.50000   0.01000  Uiso   1.00
C66    C     0.31948   0.14651   0.36227   0.01000  Uiso   1.00
H67    H     0.29119   0.16808   0.47042   0.01000  Uiso   1.00
H68    H     0.37093   0.19030   0.33691   0.01000  Uiso   1.00
H69    H     0.34428   0.08087   0.38056   0.01000  Uiso   1.00
C70    C     0.24651   0.14693   0.20894   0.01000  Uiso   1.00
C71    C     0.24090   0.19535   0.04483   0.01000  Uiso   1.00
C72    C     0.31010   0.26364   0.98014   0.01000  Uiso   1.00
C73    C     0.32159   0.36082   0.02790   0.01000  Uiso   1.00
C74    C     0.26833   0.42231   0.14880   0.01000  Uiso   1.00
H75    H     0.31309   0.45856   0.22992   0.01000  Uiso   1.00
H76    H     0.22895   0.38119   0.21899   0.01000  Uiso   1.00
H77    H     0.22798   0.46766   0.07709   0.01000  Uiso   1.00
N78    N     0.16920   0.09220   0.21379   0.01000  Uiso   1.00
H79    H     0.15612   0.05483   0.30361   0.01000  Uiso   1.00
N80    N     0.39216   0.39589   0.93930   0.01000  Uiso   1.00
C81    C     0.10879   0.19126   0.77734   0.01000  Uiso   1.00
H82    H     0.09973   0.13294   0.70404   0.01000  Uiso   1.00
H83    H     0.14824   0.23729   0.71767   0.01000  Uiso   1.00
H84    H     0.04720   0.22070   0.79337   0.01000  Uiso   1.00
C85    C     0.15587   0.16539   0.95481   0.01000  Uiso   1.00
C86    C     0.37747   0.24419   0.85859   0.01000  Uiso   1.00
C87    C     0.40020   0.15257   0.76624   0.01000  Uiso   1.00
H88    H     0.40518   0.16551   0.63855   0.01000  Uiso   1.00
H89    H     0.34989   0.10528   0.77981   0.01000  Uiso   1.00
H90    H     0.46032   0.12683   0.81939   0.01000  Uiso   1.00
N91    N     0.11470   0.10320   0.06070   0.01000  Uiso   1.00
N92    N     0.42531   0.32598   0.83665   0.01000  Uiso   1.00
H93    H     0.47133   0.33305   0.76579   0.01000  Uiso   1.00
F94    F     0.08253   0.91536   0.50000   0.01000  Uiso   1.00
F95    F     0.99011   0.00002   0.26609   0.01000  Uiso   1.00
F96    F     0.08253   0.08464   0.50000   0.01000  Uiso   1.00
C97    C     0.81948   0.64651   0.36227   0.01000  Uiso   1.00
H98    H     0.79119   0.66808   0.47042   0.01000  Uiso   1.00
H99    H     0.87093   0.69030   0.33691   0.01000  Uiso   1.00
H100   H     0.84428   0.58087   0.38056   0.01000  Uiso   1.00
C101   C     0.74651   0.64693   0.20894   0.01000  Uiso   1.00
C102   C     0.74090   0.69535   0.04483   0.01000  Uiso   1.00
C103   C     0.81010   0.76364   0.98014   0.01000  Uiso   1.00
C104   C     0.82159   0.86082   0.02790   0.01000  Uiso   1.00
C105   C     0.76833   0.92231   0.14880   0.01000  Uiso   1.00
H106   H     0.81309   0.95856   0.22992   0.01000  Uiso   1.00
H107   H     0.72895   0.88119   0.21899   0.01000  Uiso   1.00
H108   H     0.72798   0.96766   0.07709   0.01000  Uiso   1.00
N109   N     0.66920   0.59220   0.21379   0.01000  Uiso   1.00
H110   H     0.65612   0.55483   0.30361   0.01000  Uiso   1.00
N111   N     0.89216   0.89589   0.93930   0.01000  Uiso   1.00
C112   C     0.60879   0.69126   0.77734   0.01000  Uiso   1.00
H113   H     0.59973   0.63294   0.70404   0.01000  Uiso   1.00
H114   H     0.64824   0.73729   0.71767   0.01000  Uiso   1.00
H115   H     0.54720   0.72070   0.79337   0.01000  Uiso   1.00
C116   C     0.65587   0.66539   0.95481   0.01000  Uiso   1.00
C117   C     0.87747   0.74419   0.85859   0.01000  Uiso   1.00
C118   C     0.90020   0.65257   0.76624   0.01000  Uiso   1.00
H119   H     0.90518   0.66551   0.63855   0.01000  Uiso   1.00
H120   H     0.84989   0.60528   0.77981   0.01000  Uiso   1.00
H121   H     0.96032   0.62683   0.81939   0.01000  Uiso   1.00
N122   N     0.61470   0.60320   0.06070   0.01000  Uiso   1.00
N123   N     0.92531   0.82598   0.83665   0.01000  Uiso   1.00
H124   H     0.97133   0.83305   0.76579   0.01000  Uiso   1.00
Si125  Si    0.50000   0.50002   0.50000   0.01000  Uiso   1.00
Si126  Si    0.00000   0.00002   0.50000   0.01000  Uiso   1.00
Ni127  Ni    0.50000   0.50000  -0.00000   0.01000  Uiso   1.00
Ni128  Ni    0.00000   0.00000  -0.00000   0.01000  Uiso   1.00
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_ccdc_geom_bond_type
F1     Si125   1.657   .     S
F2     Si125   1.747   .     S
F2     Ni127   2.010   1_556 S
F3     Si125   1.656   .     S
C4     H5      0.980   .     S
C4     H6      0.979   .     S
C4     H7      0.981   .     S
C4     C8      1.480   .     S
C8     C9      1.398   .     D
C8     N16     1.335   .     S
C9     C10     1.474   1_556 S
C9     C23     1.394   1_556 S
C10    C9      1.474   1_554 S
C10    C11     1.400   1_554 S
C10    C24     1.399   .     D
C11    C10     1.400   1_556 S
C11    C12     1.494   .     S
C11    N18     1.337   1_556 D
C12    H13     0.980   .     S
C12    H14     0.981   .     S
C12    H15     0.980   .     S
N16    H17     0.881   .     S
N16    N29     1.337   .     S
N18    C11     1.337   1_554 D
N18    N30     1.346   .     S
N18    Ni127   2.123   .     S
C19    H20     0.980   .     S
C19    H21     0.980   .     S
C19    H22     0.980   .     S
C19    C23     1.481   .     S
C23    C9      1.394   1_554 S
C23    N29     1.338   1_554 D
C24    C25     1.495   .     S
C24    N30     1.338   .     S
C25    H26     0.982   .     S
C25    H27     0.980   .     S
C25    H28     0.977   .     S
N29    C23     1.338   1_556 D
N29    Ni128   2.184   1_656 S
N30    H31     0.880   .     S
F32    Si126   1.657   1_665 S
F33    Si126   1.747   .     S
F33    Ni128   2.010   1_556 S
F34    Si126   1.656   1_655 S
C35    H36     0.980   .     S
C35    H37     0.979   .     S
C35    H38     0.981   .     S
C35    C39     1.480   .     S
C39    C40     1.398   .     D
C39    N47     1.335   .     S
C40    C41     1.474   1_556 S
C40    C54     1.394   1_556 S
C41    C40     1.474   1_554 S
C41    C42     1.400   1_554 S
C41    C55     1.399   .     D
C42    C41     1.400   1_556 S
C42    C43     1.494   .     S
C42    N49     1.337   1_556 D
C43    H44     0.980   .     S
C43    H45     0.981   .     S
C43    H46     0.980   .     S
N47    H48     0.881   .     S
N47    N60     1.337   .     S
N49    C42     1.337   1_554 D
N49    N61     1.346   .     S
N49    Ni128   2.123   1_565 S
C50    H51     0.980   .     S
C50    H52     0.980   .     S
C50    H53     0.980   .     S
C50    C54     1.481   .     S
C54    C40     1.394   1_554 S
C54    N60     1.338   1_554 D
C55    C56     1.495   .     S
C55    N61     1.338   .     S
C56    H57     0.982   .     S
C56    H58     0.980   .     S
C56    H59     0.977   .     S
N60    C54     1.338   1_556 D
N60    Ni127   2.184   1_556 S
N61    H62     0.880   .     S
F63    Si125   1.657   .     S
F64    Si125   1.747   .     S
F64    Ni127   2.010   .     S
F65    Si125   1.656   .     S
C66    H67     0.980   .     S
C66    H68     0.979   .     S
C66    H69     0.981   .     S
C66    C70     1.480   .     S
C70    C71     1.398   .     D
C70    N78     1.335   .     S
C71    C72     1.474   1_554 S
C71    C85     1.394   1_554 S
C72    C71     1.474   1_556 S
C72    C73     1.400   1_556 S
C72    C86     1.399   .     D
C73    C72     1.400   1_554 S
C73    C74     1.494   .     S
C73    N80     1.337   1_554 D
C74    H75     0.980   .     S
C74    H76     0.981   .     S
C74    H77     0.980   .     S
N78    H79     0.881   .     S
N78    N91     1.337   .     S
N80    C73     1.337   1_556 D
N80    N92     1.346   .     S
N80    Ni127   2.123   1_556 S
C81    H82     0.980   .     S
C81    H83     0.980   .     S
C81    H84     0.980   .     S
C81    C85     1.481   .     S
C85    C71     1.394   1_556 S
C85    N91     1.338   1_556 D
C86    C87     1.495   .     S
C86    N92     1.338   .     S
C87    H88     0.982   .     S
C87    H89     0.980   .     S
C87    H90     0.977   .     S
N91    C85     1.338   1_554 D
N91    Ni128   2.184   .     S
N92    H93     0.880   .     S
F94    Si126   1.657   1_565 S
F95    Si126   1.747   1_655 S
F95    Ni128   2.010   1_655 S
F96    Si126   1.656   .     S
C97    H98     0.980   .     S
C97    H99     0.979   .     S
C97    H100    0.981   .     S
C97    C101    1.480   .     S
C101   C102    1.398   .     D
C101   N109    1.335   .     S
C102   C103    1.474   1_554 S
C102   C116    1.394   1_554 S
C103   C102    1.474   1_556 S
C103   C104    1.400   1_556 S
C103   C117    1.399   .     D
C104   C103    1.400   1_554 S
C104   C105    1.494   .     S
C104   N111    1.337   1_554 D
C105   H106    0.980   .     S
C105   H107    0.981   .     S
C105   H108    0.980   .     S
N109   H110    0.881   .     S
N109   N122    1.337   .     S
N111   C104    1.337   1_556 D
N111   N123    1.346   .     S
N111   Ni128   2.123   1_666 S
C112   H113    0.980   .     S
C112   H114    0.980   .     S
C112   H115    0.980   .     S
C112   C116    1.481   .     S
C116   C102    1.394   1_556 S
C116   N122    1.338   1_556 D
C117   C118    1.495   .     S
C117   N123    1.338   .     S
C118   H119    0.982   .     S
C118   H120    0.980   .     S
C118   H121    0.977   .     S
N122   C116    1.338   1_554 D
N122   Ni127   2.184   .     S
N123   H124    0.880   .     S
Si126  F32     1.657   1_445 S
Si126  F94     1.657   1_545 S
Si126  F95     1.747   1_455 S
Si126  F34     1.656   1_455 S
Ni127  N80     2.123   1_554 S
Ni127  F2      2.010   1_554 S
Ni127  N60     2.184   1_554 S
Ni128  N49     2.123   1_545 S
Ni128  N111    2.123   1_444 S
Ni128  F33     2.010   1_554 S
Ni128  F95     2.010   1_455 S
Ni128  N29     2.184   1_454 S